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Introduction Preliminaries Biorthogonality and Applications Orthogonality for Polynomials Interpolation and Projection Kernel The Interpolation Operator The Method of Moments Lanczos' Method The Bi-conjugate Gradient Method Fredholm Equation and Pad-Type Approximants Adjacent Biorthogonal Families One-Step Forumlas Multistep Formulas Applications Sequence Transformations Linear Multistep Methods Approximation of Series Biorthogonal Polynomials Statistics and Least Squares Appendix 1: A Direct Proof of the Christoffel-Darboux Identity and a Consequence Appendix 2: Duality in Pad-Type Approximation Appendix 3: Sylvester's and Schweins' Identities in a Vector Space References